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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 4
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Original Articles

Dicyclohexylborane-Catalyzed Hydroboration of 1-Halo-1-alkynes with 9-Borabicyclo[3.3.1]nonane

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Pages 567-572 | Received 13 Jun 1996, Published online: 20 Aug 2006
 

Abstract

A catalytic amount of dicyclohexylborane accelerates the hydroboration of 1-halo-1-alkyne (1) with 9-BBN to provide B-[(Z)-1-halo-1-alkenyl]-9-BBN (2) regio- and stereo-selectively.

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