Photochemical Rearrangements of Chiral Bicyclo[2.2.2]oct-5-en-2-Ones1 : Synthetic Communications: Vol 27, No 4

Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 27, 1997 - Issue 4

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Abstract

Photochemical oxadi-π-methane rearrangement (1,2-acyl shift) of the chiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6 , whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.

Notes

Chiral synthons from carvone Part 24. Part 23, Srikrishna, A.; Sharma, G.V.R., Submitted for publication.

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Photochemical Rearrangements of Chiral Bicyclo[2.2.2]oct-5-en-2-Ones¹

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Photochemical Rearrangements of Chiral Bicyclo[2.2.2]oct-5-en-2-Ones1

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Photochemical Rearrangements of Chiral Bicyclo[2.2.2]oct-5-en-2-Ones¹