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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 7
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Original Articles

Stereospecific Synthesis of Methyl Vinyl Ketones

A. Chamakh Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences, Campus Universitaire, 1060, Tunis, TUNISIE
,
M. M'hirsi Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences, Campus Universitaire, 1060, Tunis, TUNISIE
&
H. Amri Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences, Campus Universitaire, 1060, Tunis, TUNISIE
Pages 1157-1163 | Received 31 Oct 1996, Published online: 22 Aug 2006
 
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Abstract

A stereospecific synthesis of enones 3 by coupling reaction of α-acetoxy alkyl methyl vinyl ketones 2 and Gilman or Grignard reagents in the presence of a catalytic amount of copper (I) salt at low temperature, is described.

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