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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 13
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Original Articles

A Novel Synthesis of DL-proto-, and DL-vibo-Quercitol via 1, 4-Cyclohexadiene

Emine Salamci Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240, Erzurum, Turkiye
,
Hasan Seçen Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240, Erzurum, Turkiye
,
Yasar Sütbeyaz Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240, Erzurum, Turkiye
&
Metin Balci Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240, Erzurum, Turkiye
Pages 2223-2234 | Received 18 Nov 1996, Published online: 22 Aug 2006
 
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Abstract

Photooxygenation of 1, 4-cyclohexadiene 3 followed by reduction with LiAlH4 or thiourea gave (25/1)-cyclohex-3-ene-triol 7a. trans-Hydroxylation of triol 7a with three different methods afforded both of proto-quercitol la and vibo-quercitol 2a.

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