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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 13
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Original Articles

Friedel-Crafts Benzylation of Arenes Using FeCl3 Impregnated Montmorillonite K10.

S. G. Pai Organic Chemistry Research Laboratory, University Department of Chemical Technology, Matunga, Bombay, 400019, India
,
A. R. Bajpai Organic Chemistry Research Laboratory, University Department of Chemical Technology, Matunga, Bombay, 400019, India
,
A. B. Deshpande Organic Chemistry Research Laboratory, University Department of Chemical Technology, Matunga, Bombay, 400019, India
&
S. D. Samant Organic Chemistry Research Laboratory, University Department of Chemical Technology, Matunga, Bombay, 400019, India
Pages 2267-2273 | Received 03 Dec 1996, Published online: 22 Aug 2006
 
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Abstract

FeCl3 impregnated Montmorillonite K10 was found to catalyze the Friedel-Craftsbenzylation of arenes. Monobenzylation, with the para isomer predominating, was achieved with trace amounts of dibenzylated product.

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