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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 11
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Original Articles

Barbier-Type Allylation of Aldehydes and Ketones with Metallic Lead in Aqueous Media

Jing-Yao Zhou Department of Chemistry, Fudan University, Shanghai, 200433, PR China
,
Yu Jia Department of Chemistry, Fudan University, Shanghai, 200433, PR China
,
Guang-Fu Sun Department of Chemistry, Fudan University, Shanghai, 200433, PR China
&
Shi-Hui Wu Department of Chemistry, Fudan University, Shanghai, 200433, PR China
Pages 1899-1906 | Received 28 Oct 1996, Published online: 22 Aug 2006
 
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Abstract

Homoallylic alcohols can be obtained from allylation of aldehydes and ketones with allyl bromide promoted by metallic lead. These reactions can be carried out smoothly in aqueous media.

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