Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 13
Submit an article Journal homepage
60
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis of (E)-Nitro Olefins by Copper Mediated Addition-Elimination Reaction of Organometallics to 2-Nitro-1-phenylthiopropene

Peter Stanetty Institute of Organic Chemistry, Vienna University of Technology Getreidemarkt, 9/154, A-1060, Vienna, Austria E-mail: [email protected]
&
Manfred Kremslehner Institute of Organic Chemistry, Vienna University of Technology Getreidemarkt, 9/154, A-1060, Vienna, Austria E-mail: [email protected]
Pages 2491-2498 | Received 02 Dec 1997, Published online: 20 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The reaction of various organometallics with 2-nitro-1-phenylsulfonylpropene 2a and 2-nitro-1-phenylthiopropene 2b was investigated. While in the case of lithium and magnesium organyls the addition products 4 were formed, transmetallation with CuCN led exclusively to (E)-nitro olefins 3.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.