Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

C. Moreau Laboratoire de Chimie Organique et Organométallique, UMR 5802 CNRS, Université Bordeaux 1, F-33405, Talence, France

F. Serein-Spirau Laboratoire de Chimie Organique et Organométallique, UMR 5802 CNRS, Université Bordeaux 1, F-33405, Talence, France

M. Bordeau Laboratoire de Chimie Organique et Organométallique, UMR 5802 CNRS, Université Bordeaux 1, F-33405, Talence, France

C. Biran Laboratoire de Chimie Organique et Organométallique, UMR 5802 CNRS, Université Bordeaux 1, F-33405, Talence, France

Abstract

The sacrificial anode technique proved to be efficient for the selective and competitive silylation of 1-methylpyrrole bromides with trimethylchlorosilane and diorganodichlorosilanes. Linear and cyclic alternated 1-methyl-pyrrolylene-silanylene oligomers were obtained in good to high yields.

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Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

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Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

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