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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 14
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Original Articles

Stereoselective Synthesis of 1-Substituted (1E, 3E)-1,3-Butadienyl Phenyl Tellurides and Internal Vinylic Tellurides

Jin WukSung Department of Chemistry, Korea Advanced Institute of Science and Technology, 373–1, Kusung-Dong, Yusung-Gu, Taejon, 305-701, Korea
,
Chan PilPark Department of Chemistry, Korea Advanced Institute of Science and Technology, 373–1, Kusung-Dong, Yusung-Gu, Taejon, 305-701, Korea
,
Jun MoGil Department of Chemistry, Korea Advanced Institute of Science and Technology, 373–1, Kusung-Dong, Yusung-Gu, Taejon, 305-701, Korea
&
Dong YoungOh Department of Chemistry, Korea Advanced Institute of Science and Technology, 373–1, Kusung-Dong, Yusung-Gu, Taejon, 305-701, Korea
Pages 2635-2640 | Received 12 Dec 1997, Published online: 20 Aug 2006
 
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Abstract

1-Substituted (1E,3E)-1,3-butadienyl phenyl tellurides and internal vinylic tellurides re synthesized regio-and stereo-selectively using the preferential migration of the alkenyl or alkyl group from boron to the adjacent alkynyl sp-crbon actom.

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