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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 15
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Original Articles

Esterification in dry Media Using Ferric Perchlorate Adsorbed on Silica Gel

Anupama Parmar Department of Chemistry, Punjabi University, Patiala, 147 002
,
Jatinder Kaur Department of Chemistry, Punjabi University, Patiala, 147 002
,
Rita Goyal Department of Chemistry, Sant Longowal Institute of Engg. & Technology, Longowal, 148 106, India
,
Baldev Kumar Department of Chemistry, Punjabi University, Patiala, 147 002
&
Harish Kumar Department of Chemistry, Sant Longowal Institute of Engg. & Technology, Longowal, 148 106, India
Pages 2821-2826 | Received 19 Dec 1997, Published online: 20 Aug 2006
 
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Abstract

Adsorption of Fe(ClO4)3(H2O)6 onto chromatographic grade silica gel in the presence of alcohol (to be used for esterification) produces a supported reagent, Fe(ClO4)3(ROH)6/SiO2. This reagent, has been found effective for the rapid and high yield of esters, on grinding in the presence of carboxylic acids using pestle and mortar in the solid state.

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