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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 19
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Original Articles

The Improved Synthesis of Enantiopure (S)-N-Arylmethyl-5-Oxoprolines

Stefan Marchalin Department of Organic Chemistry, Slovak Technical University, Radlinského 9, 81237, Bratislava, Slovak republic E-mail: [email protected]
,
Katarina Kadlecikova Department of Organic Chemistry, Slovak Technical University, Radlinského 9, 81237, Bratislava, Slovak republic E-mail: [email protected]
,
Nathalie Bar Laboratoire de Chimie, Faculté des Sciences et Techniques de l'Université du Havre, 30 rue Gabriel Péri, 76600, Le Havre, France
&
Bernard Decroix Laboratoire de Chimie, Faculté des Sciences et Techniques de l'Université du Havre, 30 rue Gabriel Péri, 76600, Le Havre, France
Pages 3619-3624 | Received 19 Apr 1998, Published online: 22 Aug 2006
 
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Abstract

A mild procedure for the preparation of enantiopure N-alkylated (S)-(+)-5-oxoprolines 3a-r is described. The method starting from (S)-glutamic acid appears generally applicable to substrates with a wide range of substituents.

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