Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 20
Submit an article Journal homepage
699
Views
21
CrossRef citations to date
0
Altmetric
Original Articles

Hydroxymethylation and Carbamoylation of Di-And Tetramethylpyridines Using Radical Substitution (Minisci) Reactions

Mohammad A. AmrollahiBiyouki Chemistry Department, University of Otago, P.O. Box 56, Dunedin, New Zealand
,
Robin A. J.Smith Chemistry Department, University of Otago, P.O. Box 56, Dunedin, New Zealand
,
Jennifer J. Bedford Physiology Department, School of Medical Sciences, University of Otago, P.O. Box 913, Dunedin, New Zealand
&
John P. Leader Physiology Department, School of Medical Sciences, University of Otago, P.O. Box 913, Dunedin, New Zealand
Pages 3817-3825 | Received 27 Apr 1998, Published online: 23 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Reaction of hydroxymethyl radicals with N-methoxy 2,4- and 2,6-dimethylpyridinium salts gave 2,4,6-substituted hydroxymethylpyridines. Similar reactions with 2,3,5,6-tetramethylpyridine and derivatives failed, however 4-substitution could be achieved using a carbamoyl radical.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

One-pot bifunctionalization of unactivated alkenes, P(O)–H compounds, and N-methoxypyridinium salts for the construction of β-pyridyl alkylphosphonates
Source: Royal Society of Chemistry (RSC)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.