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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 21
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Original Articles

Conversion of Epoxides to Thiiranes Catalyzed with TiO(TFA)2 and TiCl3(Otf) in the Presence of Ammonium Thiocyanate or Thiourea

N. Iranpoor Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, Iran
&
B. Zeynizadeh Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, Iran
Pages 3913-3918 | Received 09 Feb 1998, Published online: 16 Aug 2006
 
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Abstract

TiO(CF3CO2)2 and TiCl3(CF3SO3) are efficient catalysts for the conversion of epoxides to thiiranes in the presence of ammoniun thiocyanate or thiourea under non-aqueous conditions.

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