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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 21
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Original Articles

Bismuth(III) Chloride; A Mild and Efficient Catalyst for Synthesis of Thiiranes from Oxiranes

I. Mohammadpoor-Baltork Chemistry Department, Esfahan University, Esfahan, 81744, Iran
&
H. Aliyan Chemistry Department, Esfahan University, Esfahan, 81744, Iran
Pages 3943-3947 | Received 14 May 1998, Published online: 16 Aug 2006
 
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Abstract

A simple and efficient method for the conversion of oxiranes to the corresponding thiiranes using ammonium thiocyanate (NH4SCN) and catalytic amounts of bismuth(III) chloride (BiCl3) is described. The yields obtained are excellent.

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