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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 21
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Original Articles

Reductive Cleavage of Se–Si Bond in Arylselenotrimethylsilane: A Novel Method for the Synthesis of Selenoesters

Songlin Zhang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P.R. China
&
Yongmin Zhang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P.R. China
Pages 3999-4002 | Received 14 May 1998, Published online: 16 Aug 2006
 
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Abstract

Arylselenotrimethylsilane is reduced by samarium diiodide to yield samarium arylselenolates. These new selenolate anion species reacted smoothly with acyl halides to give selenoesters.

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