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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 4
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Original Articles

One-Pot Synthesis of Nucleosides Using Bismuth(III) Bromide as Catalyst.

Jean-Yves Winum Laboratoire de Chimie Biomoléculaire, associé CNRS, Université Montpellier II cc073, Place E. Bataillon, 34095, cedex, Montpellier, 05, France
,
Mehrnaz Kamal Laboratoire de Chimie Biomoléculaire, associé CNRS, Université Montpellier II cc073, Place E. Bataillon, 34095, cedex, Montpellier, 05, France
,
Véronique Barragan Laboratoire de Chimie Biomoléculaire, associé CNRS, Université Montpellier II cc073, Place E. Bataillon, 34095, cedex, Montpellier, 05, France
,
Alain Leydet Laboratoire de Chimie Biomoléculaire, associé CNRS, Université Montpellier II cc073, Place E. Bataillon, 34095, cedex, Montpellier, 05, France
&
Jean-Louis Montero Laboratoire de Chimie Biomoléculaire, associé CNRS, Université Montpellier II cc073, Place E. Bataillon, 34095, cedex, Montpellier, 05, France
Pages 603-606 | Received 21 Jul 1997, Published online: 02 Sep 2006
 
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Abstract

A peracetylated α-D-ribofuranosyl bromide reacted with silylated heterocyclic bases in the presence of bismuth (III) bromide (a non-toxic catalyst) in a one-pot procedure to give the corresponding β-D-nucleoside in good yield.

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