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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 10
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Original Articles

t-Butyl Hypochlorite: A Powerful Electrophilic Aromatic Ring Chlorinating Agent

Istvan Lengyel Department of Chemistry, St. John's University, Jamaica, New York, 11439
,
Victor Cesare Department of Chemistry, St. John's University, Jamaica, New York, 11439
&
Ralph Stephani Department of Chemistry, St. John's University, Jamaica, New York, 11439
Pages 1891-1896 | Received 02 Nov 1997, Published online: 20 Aug 2006
 
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Abstract

t-Butyl hypochlorite is an excellent aromatic ring chlorinating agent, under mild conditions, without any catalyst, of acetanilide. High regioselectivity is observed, the product being, nearly exclusively, para-chloroacetanilide.

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