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Abstract
Acetates derived from Baylis-Hillman products were reacted with sodio dimethyl (or diethyl) malonate under Pd(0) catalysis to form E olefins as the major products. Likewise, the Heck reaction with these acetates as well as with the corresponding alcohols form a variety of useful intermediates which include trisubstituted olefinic compounds and α-benzyl β-keto esters.
1Part 8 'General Synthefic Methods'. For part 7, see Kumareswaran, R.; Gupta, A. and Vankar, Y. D. Synth. Commun. 1997, 27, 277.
2Part of this work was presented in 'ICOS-10, IUPAC at Bangalore, India, December 11- 16,1994.
Notes
1Part 8 'General Synthefic Methods'. For part 7, see Kumareswaran, R.; Gupta, A. and Vankar, Y. D. Synth. Commun. 1997, 27, 277.
2Part of this work was presented in 'ICOS-10, IUPAC at Bangalore, India, December 11- 16,1994.
Part of this work was presented in 'ICOS-10, IUPAC at Bangalore, India, December 11— 16, 1994