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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 11
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Original Articles

A Significant Effect of Triflic Acid on the Hypervalent λn-Iodane-Mediated Fragmentation of the Tertiary Cyclopropanol System

Masayuki Kirihara Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Sugitani, 2630, Toyama, 930—01, Japan
,
Satoshi Yokoyama Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Sugitani, 2630, Toyama, 930—01, Japan
&
Takefumi Momose Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Sugitani, 2630, Toyama, 930—01, Japan
Pages 1947-1956 | Received 29 Aug 1997, Published online: 20 Aug 2006
 
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Abstract

Trifluoromethanesulfonic acid enhanced the ring cleavage in the reaction of silyl tertiary cyclopropyl ethers with phenyliodine(III) diacetate in a catalytic amount.

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