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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 22
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Original Articles

A Novel and Easy De-Ethoxycarbonylation of α-Substituted Malonic Esters

Júlio O. F. Melo Depto. De Química, ICEx - Univ. Fed. de Minas Gerais, Belo Horizonte - M.G. Caixa Postal 702 - CEP. 30123-970
,
Elaine H. Teixeira Pereira Depto. De Química, ICEx - Univ. Fed. de Minas Gerais, Belo Horizonte - M.G. Caixa Postal 702 - CEP. 30123-970
,
Claudio L. Donnici Depto. De Química, ICEx - Univ. Fed. de Minas Gerais, Belo Horizonte - M.G. Caixa Postal 702 - CEP. 30123-970
,
Blanka Wladislaw Instituto de Química - Universidade de São Paulo, Caixa Postal 26077 - CEP. 05509-970, São Paulo, SP
&
Liliana Marzorati Instituto de Química - Universidade de São Paulo, Caixa Postal 26077 - CEP. 05509-970, São Paulo, SP
Pages 4179-4185 | Received 01 Jun 1998, Published online: 11 Mar 2009
 
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Abstract

The reaction of some α-substituted malonic esters with Triton B in DMSO to give the corresponding α-substituted carboxylic esters is reported.

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