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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 2
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Original Articles

Facile Formation of Samarium (III) Selenolates From Potassium Iodide Catalyzed Reaction of Samarium Metal and Diselenides, and Their Application in Synthesis of Selenoesters

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Pages 219-225 | Received 28 Apr 1998, Published online: 17 Sep 2007
 

Abstract

Samarium metal reacts with diselenides in the presence of a catalytic amount of potassium iodide to generate samarium(II1) selenolates. Samarium (111) selenolates thus formed in situ, react with acid chlorides to give selenoesters in moderate yields.

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