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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 2
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Original Articles

Allylation Of Novel β-Phenylthio Substituted gem-Difluoroallylic Bromide to Carbonyl Compounds

In Howa Jeong Department of Chemistry, Yonsei University, Wonju, 220-710, Korea
,
Myong Sang Kim Department of Chemistry, Yonsei University, Wonju, 220-710, Korea
&
Bum Tae Kim Korea Research Institute of Chemical Technology, Daejeon, 305-606, Korea
Pages 235-241 | Received 06 Apr 1998, Published online: 17 Sep 2007
 
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Abstract

The reaction of β-phenylthio substituted gem-difluoroallylic bromide 3 with aldehydes and ketones in the presence of Zn(Cu) in THF at reflux temperature afforded the corresponding homoallylic alcohols 4 in good yields.

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