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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 2
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Original Articles

A Novel Reduction of β-Ketoester with Cp2TiCl2A-PrMgBr System

Yongping Yu Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China
&
Yongmin Zhang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
Pages 243-247 | Received 23 Mar 1998, Published online: 17 Sep 2007
 
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Abstract

β-Ketoesters react with Grignard reagent in the presence of a catalytic amount of Cp2TiCl2 to afford the corresponding ketones. A possible mechanism is also proposed.

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