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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 2
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Original Articles

Microporous Solids for the Selective Bromination of a Diterpene Resin Acid

M. Alexandra Esteves Institulo National de Engenharia e Tecnologia Industrial, IBQTA, DTIQ, Estrada do Paço do Lumiw, 1699, Lisboa Codex, Portugal
,
Nama Narender Institulo National de Engenharia e Tecnologia Industrial, IBQTA, DTIQ, Estrada do Paço do Lumiw, 1699, Lisboa Codex, Portugal
,
Bárbara Gigante Institulo National de Engenharia e Tecnologia Industrial, IBQTA, DTIQ, Estrada do Paço do Lumiw, 1699, Lisboa Codex, Portugal
,
M. J. Marcelo-curto Institulo National de Engenharia e Tecnologia Industrial, IBQTA, DTIQ, Estrada do Paço do Lumiw, 1699, Lisboa Codex, Portugal
&
Fernanda Alvarez Instituto Superior Técnico, DEQ, Grupo de Zeólilos, Av. Rovisco Pais, 1096, Lisboa Codex, Portugal
Pages 275-280 | Received 13 Jul 1998, Published online: 17 Sep 2007
 
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Abstract

The liquid-phase bromination of methyl dehydroabietate with bromine or NBS in the presence of microporous solids has been investigated. The reactions were fast and easily performed and the highest yield and regioselectivity were obtained with the system bromine/montmorillonite K10.

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