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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 23
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Original Articles

A New Phase Transfer Reagent for the Addition of Dichlorocarbene to Olefins Under Mild PTC Conditions

J. Paul Jayachandran Department of Chemical Engineering, National Tsing Hua University, Hsinchu, Taiwan, 300, R.O.C
&
Maw-Ling Wang Department of Chemical Engineering, National Chung Cheng University, Chiayi, Taiwan, 621, R.O.C
Pages 4101-4112 | Received 22 Jan 1999, Published online: 17 Sep 2007
 
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Abstract

A three-step synthetic route to a novel water soluble phase transfer reagent, Diquat (Dq-Br), viz., 2-benzilidine- N,N,N,N',N',N'- hexaethyl propane-1,3 diammonium dibromide and its utility in various dichlorocarbenations to olefins are described.

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