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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 23
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Original Articles

Reaction of N-(Benzyloxycarbonyl)aminobenzyl-phosphonous Acid with Ethyl Orthoformate

Adrian Stano Institute of Organic Chemistry, Biochemistry and Biotechnology, University Technology of Wroclaw, Wybrzeze Wyspiańskiego 27, 50-370, Wroclaw, Poland
,
Artur Mucha Institute of Organic Chemistry, Biochemistry and Biotechnology, University Technology of Wroclaw, Wybrzeze Wyspiańskiego 27, 50-370, Wroclaw, Poland
&
Pawel Kafarski Institute of Organic Chemistry, Biochemistry and Biotechnology, University Technology of Wroclaw, Wybrzeze Wyspiańskiego 27, 50-370, Wroclaw, Poland
Pages 4269-4277 | Accepted 01 Apr 1999, Published online: 17 Sep 2007
 
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Abstract

Reaction of N-(benzyloxycarbonyl)aminobenzylphosphonous acid with ethyl orthoformate afforded two major products diethyl N-(benzyloxycarbonyl)aminobenzylphosphhite and ethyl (diethoxymethyl)[N-(benzyloxy-carbonyl)aminobenzyl]phosphmate, a product of addition of phosphonous acid to orthoformate.

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