Microwave Activation in Organic Synthesis: Natural Indian Clay, EPIC^R EPZG^R and EPZ10^R as Novel Heterogenous Catalysts for Rapid Synthesis of Nitriles from Aldoximes in Absence of Solvent

B. P. Bandgar Organic Chemistry Research Laboratory, School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431 606, India

V. S. Sadavarte Organic Chemistry Research Laboratory, School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431 606, India

K. R. Sabu Clay and Minerals Division, RRL, Trivandrum, India

Abstract

The Conversion of aldoximes into nitriles was carried out in the absence of solvent under microwave irradiation using environmentally-friendly catalysts like natural kaolinitic clay, EPIC^R EPZG^R and EPZ10^R. Acceleration of reaction rate, simple work-up and formation of clean Products are salient features of this method.

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Microwave Activation in Organic Synthesis: Natural Indian Clay, EPIC^R EPZG^R and EPZ10^R as Novel Heterogenous Catalysts for Rapid Synthesis of Nitriles from Aldoximes in Absence of Solvent

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Microwave Activation in Organic Synthesis: Natural Indian Clay, EPICR EPZGR and EPZ10R as Novel Heterogenous Catalysts for Rapid Synthesis of Nitriles from Aldoximes in Absence of Solvent

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Microwave Activation in Organic Synthesis: Natural Indian Clay, EPIC^R EPZG^R and EPZ10^R as Novel Heterogenous Catalysts for Rapid Synthesis of Nitriles from Aldoximes in Absence of Solvent