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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 19
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Original Articles

A Facile Regio- and Stereocontrolled Synthesis of (z)-1,3-Enylnylstannanes via Cross Coupling of (E)-α-Iodovinylstannanes with Terminal Alkynes

Xian Huang Department of Chemistry, Zhejiang University, (Campus Xixi), Hangzhou, 310028, P. R. China
&
Ping Zhong Department of Chemistry, Zhejiang University, (Campus Xixi), Hangzhou, 310028, P. R. China
Pages 3425-3434 | Accepted 11 Feb 1999, Published online: 17 Sep 2007
 
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Abstract

Conjugated enynes bearing a stannyl group were conveniently obtained under mild condition via the cross coupling of the corresponding (E)-α-iodovinyktannanes with terminal alkynes in the presence of Pd(PPh3) and CuBr.

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