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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 20
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Original Articles

An Expedient Synthesis of 14,14-Dimethyl-3,7-diazatricyclo[8.3.11,10.03.8]tetradec-7-en-4-one-12α-yl Cinnamate, an Unusual Heterocyclic Compound Resembling the A/B/C Core of Taxanes

Federica Orvieto Dipartimento Farmaco Chimico Tecnologico, Università degli Studi di Siena Banchi di Sotto, 55-53100, Siena, Italy; IRBM, Via Pontina km 30,600, 00040, Pomezia, Roma, Italy
,
Maurizio Botta Dipartimento Farmaco Chimico Tecnologico, Università degli Studi di Siena Banchi di Sotto, 55-53100, Siena, Italy
,
Federico Corelli Dipartimento Farmaco Chimico Tecnologico, Università degli Studi di Siena Banchi di Sotto, 55-53100, Siena, Italy
&
Steven Harper Dipartimento Farmaco Chimico Tecnologico, Università degli Studi di Siena Banchi di Sotto, 55-53100, Siena, Italy; IRBM, Via Pontina km 30,600, 00040, Pomezia, Roma, Italy
Pages 3635-3649 | Received 18 Sep 1998, Accepted 20 Nov 1998, Published online: 17 Sep 2007
 
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Abstract

A six-step, high yielding synthesis of the title compound, which can be regarded as a model compound for the preparation of aza-analogues of taxanes, is described.

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