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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 7
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Original Articles

Haloetherification of Alkenylboronic Esters as a New Route to α-Halo Boronic Esters

S. Baba Synihèse et Electrosynthèse Organiques, associé au CNRS, Université de Rennes I, Campus de Beaulieu, 35042, Rennes Cedex, France
,
F. Leroy Synihèse et Electrosynthèse Organiques, associé au CNRS, Université de Rennes I, Campus de Beaulieu, 35042, Rennes Cedex, France
,
C. Le Goaster Synihèse et Electrosynthèse Organiques, associé au CNRS, Université de Rennes I, Campus de Beaulieu, 35042, Rennes Cedex, France
,
A. Jegou Synihèse et Electrosynthèse Organiques, associé au CNRS, Université de Rennes I, Campus de Beaulieu, 35042, Rennes Cedex, France
&
B. Carboni Synihèse et Electrosynthèse Organiques, associé au CNRS, Université de Rennes I, Campus de Beaulieu, 35042, Rennes Cedex, France
Pages 1183-1194 | Accepted 08 Aug 1998, Published online: 17 Sep 2007
 
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Abstract

Inter- and intramolecular haloetherification reactions of various alkenyiboronic esters are used as key steps in the preparation of borylated vinylic epoxides and tetrahydrofuran- or tetrahydropyran-substituted a-iodoboronic esters.

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