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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 8
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Original Articles

Chlorine Substitution Reactions using Trichloroisocyanuric Acid with Triphenylphosphine

Gene A. Hiegel Department of Chemistry and Biochemistry, California State University, Fullerton, Fullerton, California, 92834, USA
,
Jenny Ramirez Department of Chemistry and Biochemistry, California State University, Fullerton, Fullerton, California, 92834, USA
&
Robert K. Barr Department of Chemistry and Biochemistry, California State University, Fullerton, Fullerton, California, 92834, USA
Pages 1415-1419 | Received 13 Oct 1998, Published online: 17 Sep 2007
 
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Abstract

Trichloroisocyanuric acid with triphenylphosphine in anhydrous acetonitrile will convert alcohols into alkyl halides, carboxylic acids into acid chlorides, 1, 3-diketones into vinyl chlorides, and amides into nitriles.

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