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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 9
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Original Articles

Oxidation By Manganese Dioxide (mno2) Catalysed With H2SO4/silica gel. Efficient solvent-Free Oxdation Of Thioethers To Their Corresponding Sulfoxides

H. Firouzabadi Chemistry Department, Shiraz University, Shiraz, 71454, Iran
&
M. Abbasi Chemistry Department, Shiraz University, Shiraz, 71454, Iran
Pages 1485-1491 | Received 23 Jul 1998, Published online: 17 Sep 2007
 
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Abstract

H2SO4 mixed with silica gel (1:2) by weight produces a white powder which is an effective catalyst for the oxidation of thioethers to their corresponding sulfoxide by Mn02 under solvent-free conditions.

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