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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 15
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Original Articles

Trimethylammonium Chlorochromate Adsorbed on Alumina: An Efficient and Convenient Reagent for the Oxidative Cleavage of 4-Phenylsemicarbazones and Semicarbazones to Their Parent Carbonyl Compounds

Hui Gong Department of Chemistry, Henan Normal University, Xinxiang, 453002, Henan, P. R. China
&
Gui-Sheng Zhang Department of Chemistry, Henan Normal University, Xinxiang, 453002, Henan, P. R. China
Pages 2591-2596 | Accepted 12 Dec 1998, Published online: 25 Sep 2007
 
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Abstract

Deprotection of 4-phenylsemicarbazones and semicarbazones to their parent aldehydes and ketones in high yields has been carried out by using trimethylammonium chlorochromate adsorbed on alumina as selective oxidant under mild conditions.

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