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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 24
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Original Articles

Lithium Tetrafluoborate Catalyzed Ferrier Rearrangement — Facile Synthesis of Alkyl 2,3-Unsaturated Glycopyranosides

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Pages 4299-4305 | Published online: 25 Sep 2007
 

Abstract

Treatment of tri-O acetyl-D-galactal 1 and tri-O-acetyl-D-glucal 2 with diverse alcohols in the presence of LiBF4 in CH3CN, furnished alkyl 2,3-unsaturated glycopyranosides 3-18 (50-86%).

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