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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 24
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Original Articles

Improved Cs2Co3 Promoted O-Alkylation of Phenols

Jay P. ParrishDepartment of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida, 33620-5250, U.S.A.;Drug Discovery Program, H. Lee Moffitt Cancer Center & Research Institute, 12902 Magnolia Drive, Tampa, Florida, 33612-9497, U.S.A.
,
Bhuvana SudaresanDepartment of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida, 33620-5250, U.S.A.;Drug Discovery Program, H. Lee Moffitt Cancer Center & Research Institute, 12902 Magnolia Drive, Tampa, Florida, 33612-9497, U.S.A.
&
Kyung Woon JungDepartment of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida, 33620-5250, U.S.A.
Pages 4423-4431 | Received 30 Apr 1999, Published online: 25 Sep 2007
 
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Abstract

Cesium carbonate mediated O-alkylation of phenols was carried out under mild conditions to give the corresponding phenol ethers exclusively. The methodology is more efficient than previous methods since harsh conditions such as higher temperatures and longer reaction times are avoided.

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