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The influence of persulphate ions on the radiosensitivity of dilute aqueous solutions of ribonuclease and lysozyme has been studied under a vatiety of conditions. Rate-constants for reactions of the sulphate radical, SO4
, with a variety of solutes and transient product spectra of some of these reactions are reported.
The presence of persulphate ions in general enhances the radiation sensitivity; in nitrous-oxide-saturated persulphate solution, a chain reaction has been demonstrated.
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