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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 2
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Original Articles

SUZUKI CROSS-COUPLING REACTIONS OF NONRACEMIC VINYLBORONO-α-AMINO ACIDS

Sylvain Collet Université de Rennes I, Synthèse et Electrosynthèse organiques, UMR 6510, Avenue du général Leclerc, Rennes Cédex, 35042, France
,
Renée Danion-Bougot Université de Rennes I, Synthèse et Electrosynthèse organiques, UMR 6510, Avenue du général Leclerc, Rennes Cédex, 35042, France
&
Daniel Danion Université de Rennes I, Synthèse et Electrosynthèse organiques, UMR 6510, Avenue du général Leclerc, Rennes Cédex, 35042, France
Pages 249-255 | Received 06 Apr 2000, Published online: 16 Aug 2006
 
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Abstract

Vinylborono-α-amino acids undergo Suzuki coupling with vinylic or aromatic halides, allowing an easy access to stereodefined unsaturated nonproteinogenic α-amino acids. With cesium fluoride as the base, the protective groups are not affected.

Acknowledgments

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