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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 3
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Original Articles

PREPARATION OF 2,3-EPOXYCYCLOALKANONES FROM BICYCLO[n.1.0]ALKAN-1-OLS

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Pages 349-357 | Received 13 Jan 2000, Published online: 09 Nov 2006
 

Abstract

Copper- or iron-catalyzed oxidative rearrangement of bicy- clo[n.1.0]alkan-1-ols yields 3-hydroperoxycycloalkanones and/or bicyclic peroxyhemiketals, which are transformed into 2,3-epoxy- cycloalkanones by treatment with a base.

Acknowledgments

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