THE HIGH STEREOSELECTIVE SYNTHESIS OF β-ALKYNYL-ENOL PHOSPHATES: Synthetic Communications: Vol 31, No 3

Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 31, 2001 - Issue 3

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Abstract

A high stereoselective synthesis for β-alkynyl-enol phosphates from β-alkynyl ketone and dialkyl phosphite, via Atherton--Todd reaction, was reported. NaH as base gave a nearly pure Z-isomer.

ACKNOWLEDGMENT

The project was supported by the National Science Foundation of China.

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THE HIGH STEREOSELECTIVE SYNTHESIS OF β-ALKYNYL-ENOL PHOSPHATES

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THE HIGH STEREOSELECTIVE SYNTHESIS OF β-ALKYNYL-ENOL PHOSPHATES

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ACKNOWLEDGMENT

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