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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 6
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Original Articles

GENERATION AND REACTIVITY OF 1,2-DILITHIOINDOLE

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Pages 947-951 | Received 27 Mar 2000, Published online: 09 Nov 2006
 

Abstract

The generation of a 1,2-dianion (1) from 2-iodoindole is described. This dianion reacts at the carbanionic center with a range of electrophiles to give 2-substituted indoles in good yields.

ACKNOWLEDGMENTS

The authors thank Dr. S. J. Byard for NMR spectra and Dr. D. I. Smith for helpful discussions.

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