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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 11
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Original Articles

HYPERVALENT IODINE IN SYNTHESIS. 65: A NEW ROUTE TO SYNTHESIZE N-ACYLBENZOTRIAZOLES VIA PALLADIUM CATALYZED CARBONYLATION OF BENZOTRIAZOLE AND HYPERVALENT IODONIUM SALTS IN THE PRESENCE OF CARBON MONOXIDE

Li Wang Department of Chemistry, Zhejiang University, (XiXi Campus), Hangzhou, 310028, P.R. China
&
Zhen-Chu Chen Department of Chemistry, Zhejiang University, (XiXi Campus), Hangzhou, 310028, P.R. China
Pages 1633-1637 | Received 12 Jun 2000, Published online: 09 Nov 2006
 
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Abstract

N-acylbenzotriazoles are obtained directly in fair yields by palladium-catalyzed carbonylation of diaryliodonium salts with benzotriazoles in the presence of carbon monoxide.

ACKNOWLEDGMENT

We appreciate the financial support of the National Science Foundation of China (Project 29472036).

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