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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 8
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Original Articles

THE PAUSON-KHAND REACTION IN SYNTHESIS OF BICYCLIC RIGID α-AMINO ACIDS

Jing Wang Department of Chemistry, University of Oslo, Oslo, N-0315, Norway
,
Mette Lene Falck-Pedersen Department of Chemistry, University of Oslo, Oslo, N-0315, Norway
,
Christian Rømming Department of Chemistry, University of Oslo, Oslo, N-0315, Norway
&
Kjell Undheim Department of Chemistry, University of Oslo, Oslo, N-0315, Norway
Pages 1141-1148 | Received 17 Apr 2000, Published online: 09 Nov 2006
 
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Abstract

The combination of intramolecular Pauson-Khand methodology for Co2(CO)8 mediated cyclization, and the Schöllkopf chiral auxiliary for stereoselective preparation of appropriate 1,6-heptenynes constitutes a powerful method for the preparation of rigidified bicyclic α-amino acids.

Acknowledgments

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