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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 11
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Original Articles

A SIMPLE STEREOSELECTIVE ONE POT CONVERSION OF COMPOUNDS WITH A DIMETHYLAMINOMETHYLENE GROUP INTO ENOL ESTERS

Lovro Selič Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, Ljubljana, Slovenia, 1000
,
Lucija Jukić Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, Ljubljana, Slovenia, 1000
,
Gorazd Soršak Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, Ljubljana, Slovenia, 1000
,
Simona Golič Grdadolnik L01, Department of NMR and Molecular Modeling, National Institute of Chemistry, Hajdrihova 19, POB 3440, Ljubljana, Slovenia, 1000
&
Branko Stanovnik Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, Ljubljana, Slovenia, 1000
Pages 1743-1752 | Received 04 Jun 2000, Published online: 09 Nov 2006
 
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Abstract

A simple stereoselective synthesis of 2Z and 2Z,1′E alkyl 3-acyloxy-2-(2,2-disubstituted ethenyl) aminopropenoates 4 from alkyl 2-(2,2-disubstituted ethenyl)amino-3-dimethylaminopropenoates 1 in 12–91% yield is presented.

ACKNOWLEDGMENT

The authors wish to express their gratitude to the Ministry of Science and Technology, Slovenia, for their financial support.

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