ENANTIOSELECTIVE HYDROGENATION OF KETONE OXIME CATALYZED BY IR-DPAMPP COMPLEX

Yinong Xie Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China

Aiqiao Mi Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China

Yaozhong Jiang Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China

Hui Liu Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China

Abstract

A catalyst system, Ir(I)-DPAMPP-iodide, was found to be efficient in the asymmetric hydrogenation of ketone oxime with the highest enantioselectivity of 93% ee.

ACKNOWLEDGMENTS

We are grateful for the financial support from the National Science Foundation of China (No. 29790124 and 29972040).

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ENANTIOSELECTIVE HYDROGENATION OF KETONE OXIME CATALYZED BY IR-DPAMPP COMPLEX

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ENANTIOSELECTIVE HYDROGENATION OF KETONE OXIME CATALYZED BY IR-DPAMPP COMPLEX

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ACKNOWLEDGMENTS

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