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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 22
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Original Articles

A FACILE ONE POT SYNTHESIS OF m-TERPHENYL AND BIARYL DERIVATIVES

Vellingiri Raghukumar Department of Organic Chemistry, University of Madras Guindy Campus, Chennai, 600 025, India
,
Periyasamy Murugan Department of Organic Chemistry, University of Madras Guindy Campus, Chennai, 600 025, India
&
Vayalakkavoor T. Ramakrishnan Department of Organic Chemistry, University of Madras Guindy Campus, Chennai, 600 025, India
Pages 3497-3505 | Received 25 Jan 2001, Published online: 22 Aug 2006
 
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Abstract

An efficient synthesis of m-terphenyl was achieved by treatment of chalcone with malononitrile using either piperidine or morpholine and biaryl derivatives were obtained from α,β unsaturated ketones with malononitrile using pyrrolidine as a base.

ACKNOWLEDGMENT

We gratefully acknowledge CSIR and UGC (Special Assistance Programme) New Delhi for financial support. SPIC Science foundation, Chennai for NMR data. Dr. S. Muthusamy, CSMCRI, Bhavnagar, Gujarat for providing elemental analysis.

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