INDIUM MEDIATED REDUCTIVE ACYLATIONS OF NITROARENES TOWARDS N,O-DIACYLATED N-ARYLHYDROXYLAMINES^*

Byeong Hyo Kim Department of Chemistry, Kwangwoon University, Seoul, 139-701, South KoreaCorrespondence[email protected]

Jae Wook Cheong Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea

Rongbi Han Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea

Young Moo Jun Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea

Woonphil Baik Department of Chemistry, Myong Ji University, Kyung Ki Do, South Korea

Byung Min Lee Korea Research Institute of Chemical Technology, Taejon, South Korea

Abstract

By applying indium, Ac₂O, MeOH, and catalytic amount of InCl₃ in CHCl₃ solution, nitroarenes were transformed into N,O-diacylated N-arylhydroxylamines in moderate to excellent yields.

^*Dedicated to Professor Jack W. Timberlake on the occasion of his 60th Birthday.

ACKNOWLEDGMENTS

This work was supported by the Brain Korea 21 project and partly by Kwangwoon University in the year 2000.

Notes

^*Dedicated to Professor Jack W. Timberlake on the occasion of his 60th Birthday.

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INDIUM MEDIATED REDUCTIVE ACYLATIONS OF NITROARENES TOWARDS N,O-DIACYLATED N-ARYLHYDROXYLAMINES^*

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INDIUM MEDIATED REDUCTIVE ACYLATIONS OF NITROARENES TOWARDS N,O-DIACYLATED N-ARYLHYDROXYLAMINES*

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INDIUM MEDIATED REDUCTIVE ACYLATIONS OF NITROARENES TOWARDS N,O-DIACYLATED N-ARYLHYDROXYLAMINES^*