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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 24
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Original Articles

HIGHLY SELECTIVE OXIDATION OF PRIMARY AND SECONDARY BENZYLIC ALCOHOLS BY KMnO4/ZrOCI2 8H2O IN DIETHYL ETHER

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Pages 3859-3862 | Received 10 Feb 2001, Published online: 09 Nov 2006
 

Abstract

Zirconyl chloride octahydrate-potassium permanganate is used for highly selective and efficient oxidation of primary and secondary benzylic alcohols to the corresponding carbonyl compounds under mild condition. Over-oxidation of aldehydes to carboxylic acids and damage to carbon–carbon double bond is not observed by this method.

ACKNOWLEDGMENTS

The authors are grateful to National Research Council of I.R. for grant No. 464 and Shiraz University Research Council for the partial support of this work.

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