Reaction of Arylglyoxals with Electron‐Rich Benzenes and π‐Excessive Heterocycles. Facile Synthesis of Heteroaryl α‐Acyloins

Sergey P. Ivonin Department of Organic Chemistry, Dnepropetrovsk National University, Nauchnaya Street 13, Dnepropetrovsk, 49050, UkraineCorrespondence[email protected]

Andrey V. Lapandin Department of Organic Chemistry, Dnepropetrovsk National University, Nauchnaya Street 13, Dnepropetrovsk, 49050, Ukraine

Andrey A. Anishchenko Department of Organic Chemistry, Dnepropetrovsk National University, Nauchnaya Street 13, Dnepropetrovsk, 49050, Ukraine

Vasilii G. Shtamburg Department of Organic Chemistry, Dnepropetrovsk National University, Nauchnaya Street 13, Dnepropetrovsk, 49050, Ukraine

Abstract

The reaction of arylglyoxals and their hydrates with electron‐rich benzenes and π‐excessive heterocycles, if conducted in the absence of catalysts, affords α‐benzoins.

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Acknowledgment

We acknowledge the financial support of this work provided by the Ministry of Education and Science of Ukraine (Grant No. 0101U001529).

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Reaction of Arylglyoxals with Electron‐Rich Benzenes and π‐Excessive Heterocycles. Facile Synthesis of Heteroaryl α‐Acyloins

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Reaction of Arylglyoxals with Electron‐Rich Benzenes and π‐Excessive Heterocycles. Facile Synthesis of Heteroaryl α‐Acyloins

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