Abstract
The rate constant for the reaction of NO with ·O2− was determined to be (6.7 ± 0.9) × 109 1 mol−1 s−1, considerably higher than previously reported. Rate measurements were made from pH 5.6 to 12.5 both by monitoring the loss of ·O2− and the formation of the product −OONO. The decay rate of −OONO, in the presence of 0.1 moll−1 formate, ranges from 1.2s−1 at pH 5 to about 0.2s−1 in strong base, the latter value probably reflecting catalysis by formate.