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Free Radical Research Communications Volume 18, 1993 - Issue 4
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Original Article

Free Radical Production During Photo-Assisted Nadph Reduction of four α-Nitroarenofurans

Roger Zalma Laboratoire de Réactivité de Surface et Structure, Université Pierre et Marie Curie, URA 1106 CNRS, 4 place Jussieu, 75252, Paris Cedex 05, France
,
Helene Strapelias Institut Curie, Section de Physique et Chimie, URA 198 CNRS, 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France
,
Odilon Chalvet Institut Curie, Section de Physique et Chimie, URA 198 CNRS, 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France
,
Jean-Pierre Buisson Institut Curie, Section de Biologie, URA 1387 CNRS. 26 rue d'Ulm, 75231, Paris Cedex 05, France
,
Henri Pezerat Laboratoire de Réactivité de Surface et Structure, Université Pierre et Marie Curie, URA 1106 CNRS, 4 place Jussieu, 75252, Paris Cedex 05, France
,
Pierre Demerseman Institut Curie, Section de Biologie, URA 1387 CNRS. 26 rue d'Ulm, 75231, Paris Cedex 05, France
&
Maurice Duquesne Institut Curie, Section de Physique et Chimie, URA 198 CNRS, 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France
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Pages 229-237 | Received 10 Jul 1992, Published online: 07 Jul 2009
 
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Abstract

Generation of radical anions during NADPH reduction of four mutagenic and genotoxic α-nitroarenofurans was examined. ESR showed that free radicals were generated during reduction solely in the presence of light. Computer simulations of ESR spectra were in good agreement with the experimental ones.

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